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              1. Isopropylmagnesium chloride-lithium chloride complex 異丙基氯化鎂-氯化锂

                規格: 1.3 M solution in THF, SpcSeal
                CAS: 745038-86-2
                産品編号: H53317
                MDL: MFCD07784514
                品牌: INFI
                Chemical NameIsopropylmagnesium chloride-lithium chloride complex
                Synonym Turbo Grignard 異丙基氯化鎂氯化锂絡合物 溶液
                MDL NumberMFCD07784514
                PubChem Substance ID24884252
                CAS Number745038-86-2
                EC Number250-023-7
                Beilstein Registry Number2384789
                Chemical Name Translation異丙基氯化鎂-氯化锂
                LabNetwork Molecule IDLN00163618
                GHS Symbol
                WGK Germany3
                Precautionary statements
                • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 遠離熱源/火花/明火/熱的表面。——禁止吸煙。
                • P233 Keep container tightly closed. ?保持容器密閉。
                • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉塵/煙/氣體/煙霧/蒸汽/噴霧。
                • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防護手套/防護服/眼睛的保護物/面部保護物。
                • P305+P351+P338
                • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或醫生/醫師。
                  Signal word Danger
                  Hazard statements
                  • H314 Causes severe skin burns and eye damage 導緻嚴重的皮膚灼傷和眼睛損傷
                  • H351 Suspected of causing cancer 懷疑緻癌
                  • H225 Highly flammable liquid and vapour 高度易燃液體和蒸氣
                  • H335 May cause respiratory irritation 可能導緻呼吸道刺激
                    Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
                    Hazard Codes 4.3 F,C
                    Safety Statements
                    • S16 Keep away from sources of ignition - No smoking 遠離火源,禁止吸煙;
                    • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接觸後,立即用大量水沖洗并征求醫生意見;
                    • S33 Take precautionary measures against static discharges 對靜電采取預防措施;
                    • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适當的防護服、手套和眼睛/面保護;
                    • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火時使用(指明具體的消防器材種類,如果用水增加危險,注明“禁止用水”
                    • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 發生事故時或感覺不适時,立即求醫(可能時出示标簽);
                    • S7/8 Keep container tightly closed and dry 保存在嚴格密閉容器中,保持幹燥;
                      Risk Statements
                      • R11 Highly flammable 非常易燃
                      • R14/15 Reacts violently with water, liberating extremely flammable gases 遇水劇烈反應,釋放出高度可燃氣體
                      • R19 May form explosive peroxides 可能生成易爆的過氧化物質
                      • R34 Causes burns 會導緻灼傷
                      • R36/37/38 Irritating to eyes, respiratory system and skin 對眼睛、呼吸系統和皮膚有刺激性
                        Packing GroupI
                        UN Number 3399
                        Storage condition 充氩氣保存 Air & Moisture Sensitive
                      • ⑴. 由于鎂原子直接和碳鏈相連,極化作用使鄰近鎂原子的那個碳原子呈負電性,使得C-Mg鍵極具反應活性。爲了保證該産品不發生其他反應,反應一般在醚類溶劑裏進行,常用的有乙醚或四氫呋喃。
                      • ⑵. 有強烈的親核性質,可與物質中的活潑氫(如水、乙醇的羟基氫、乙炔的末端氫)反應,生成相應的烴基。
                      • ⑶. 與CO2或O2的反應,可以與二氧化碳或氧氣發生親核加成反應生成增加一個碳的羧酸或同碳數的過氧化合物.格氏試劑與二氧化碳的加成反應在有機合成中也有着重要的意義,不僅通過生成新的 C-C 鍵實現了碳鏈的增長,而且恰到好處地
                      • 745038-86-2 H53317 Isopropylmagnesium chloride-lithium chloride complex


                        Mol. Formula(CH3)2CHMgCl · LiCl
                        Mol. Weight145.24
                        Flash Point-17°(1.4°F)
                        Mol. FormulaC3H7Cl2LiMg
                        Mol. Weight145